李世清，男，漢族，1989年9月出生于湖南省邵陽市，理學博士，2017年6月進入太阳成tyc9728，從事教學與科研工作。

一、教育背景： 

2008/9-2012/6 雲南大學化學科學與工程學院，化學，本科（畢業論文導師：林軍）

2012/9-2014/6 四川大學，化學學院，有機化學，碩士（導師：高戈/遊勁松） 

2014/9-2017/6 四川大學，化學學院，有機化學，博士（導師：高戈/遊勁松）

2017/6-2021/11 太阳成tyc9728，太阳成tyc9728，講師

2022/9-2023/7 南開大學，化學學院，訪問學者（合作導師：朱守非/趙東兵）

2021/11至今 太阳成tyc9728，太阳成tyc9728，副教授

二、主講課程：

《有機化學》、《大學化學》、《普通化學》、《無機化學》

三、研究方向： 

有機合成方法學（新試劑與新反應）、C-H鍵功能化/串聯反應與機制研究、高價碘化學、有機光電材料和藥物分子的設計與合成。課題組主頁：https://www.x-mol.com/groups/LI_Shiqing-GLUT

四、主持的科研項目：

（1）國家自然科學基金，地區基金項目，22261013，環狀酸酐介導無痕策略促使無機肼轉化成有機含氮氮雙鍵化合物研究，2023.01-2026.12，33萬。

（2）國家自然科學基金，青年基金項目，22001049，C-H活化/聯導向基策略一步構築（軸手性）聯異喹啉衍生物及其金屬螯合物的應用，2021.01-2023.12，24萬。

（3）廣西自然科學基金，青年基金項目，2020GXNSFBA297003，2021.01-2023.12，8萬。

（4）廣西自然科學基金聯合資助培育項目，2018GXNSFAA294037，2019.01-2021.04，20萬。

（5）廣西科技基地和人才專項，AD19245095，2020.01-2022.12，10萬。

五、代表性成果（論文）

2023

[24] Y. Yang, R. Xie, Y. Wang, P. Zhu, J. Wang, S. Li*. Efficient synthesis of benzo[c]cinnolines and azoarenes via dual C−N coupling of phthalhydrazide and trivalent halogen reagents. Org. Chem. Front. 2023, DOI: 10.1039/D3QO00391D. (SCI一區)

 

[23] C. Wen, Y. Wang, Y. Yang, Y.-N. Tian, J. Wang, S. Li*. Hydrazone-oxime Selectively Directed Redox-Neutral [4+2] Annulations Cascade with Alkynes and Iodonium Ylides to Build 1,1′-Biisoquinoline Mono‑N‑oxides. Org. Lett. 2023, 25, 2616–2621. (SCI一區)

[22] R. Xie,^‖ Y. Xiao,^‖ Y. Wang, Z.-W. Xu, N. Tian, S. Li*, M.-H. Zeng*. Hydrazine−Halogen Exchange Strategy Toward N=N-Containing Compounds and Process Tracking for Mechanistic Insight. Org. Lett. 2023, 14, 2415–2419. (^‖Equal contribution) (SCI一區，封面文章)

    

[21] Y. Wang, Y.-N. Tian, S. Ren, R. Zhu, B. Huang, Y. Wen, S. Li*. Metal-free homo-/cross-anion–cation coupling of cyclic diaryl λ³-bromanes. Org. Chem. Front. 2023, 10, 793–798. (SCI一區)

[20] Y.-N. Tian, S. Lv, L. Huang, C. Wen, Y. Yang, X. Kong, Q. Zhu*, S. Li*. Experimental and computational studies on rhodium-catalyzed C4(5)_aryl−H activation/annulations of imidazoles with alkynes: facile synthesis of six types of N-heterocycles. Org. Chem. Front. 2023, 10, 83−91. (SCI一區)

 

2022

 

[19] L. Huang, Y.-N. Tian, S. Ren, J. Wang, Y. Xiao, Q. Zhu*, S. Li*. Palladium-catalysed dual ring-opening [3 + 4] annulation of isatoic anhydrides with cyclic iodoniums to build tribenzo[b,d,f]azepines and a mechanistic DFT study. Org. Chem. Front. 2022, 9, 6259-6264. (SCI一區)

 

[18] S. Lv, Y.-N. Tian, Y. Yang, C. Wen, S. Li*. Rh(III)-Catalyzed One-Pot Three-Component Diannulation of Benzils, Ammonium Acetate, and Alkynes to Build 1,1′-Biisoquinolines. J. Org. Chem. 2022, 87, 16019−16025. (SCI二區)

 

[17] L. Huang‡, R. Xie‡, C. Wen, Y. Yang, Y. Wang, S. Ren, B. Huang, S. Li*. Decarbonylative /decarboxylative [4 + 2] annulation of phthalic anhydrides and cyclic iodoniums towards triphenylenes. Org. Biomol. Chem. 2022, 20, 3913–3916. (‡ Equal contribution, Highlighted by Synfacts) (SCI三區)

[16] Y. Wang‡, Y. Yu‡(本科生), R. Xie, Y.-N. Tian, L. Huang, S. Lv, X. Meng, X. Kong, S. Li*. Cu/Fe-mediated N(sp²)-arylation/alkenylation of pyridines with aryl-/alkenylboronic acids to yield versatile cationic materials. New J. Chem. 2022, 46, 2320–2325. (‡ Equal contribution) (SCI三區)

2021

[15] Y. Wang (推免至華中師範大學讀博), R. Xie, L. Huang, Y.-N. Tian, S. Lv, X. Kong, S. Li*. Divergent synthesis of unsymmetrical azobenzenes via Cu-catalyzed C–N coupling. Org. Chem. Front. 2021, 8, 5962–5967. (SCI一區)

 

[14] X. Kong, R. Luo, H. Gong, D. Chen, S. Yang, S. Li*, G. Wang*, Z. He*. Discotic liquid crystals with aggregation-induced emission properties based on tetraphenylethylene and triphenylene derivatives. Mol. Cryst. Liq. Cryst. 2021, 724, 26−37.

2020

[13] S. Li*, H. Lv, R. Xie, X. Ye, X. Kong*. The C−H Activation/Bidirecting Group Strategy for Selective Direct Synthesis of Diverse 1,1′-Biisoquinolines. Org. Lett. 2020, 22, 4207−4212. (SCI一區)

 

[12] R. Xie,^# H. Lv,^# X. Ye, X. Kong*, S. Li*. Cu-Catalyzed tandem N-arylation of phthalhydrazides with cyclic iodoniums to yield dihydrobenzo[c]cinnolines. Org. Biomol. Chem. 2020, 18, 4824−4830. (^# Equal contribution) (SCI三區)

[11] Y. Yu (本科生), H. Lv, S. Li*. The C–H functionalization of organic cations: an interesting and fresh journey. Org. Biomol. Chem. 2020, 18, 8810–8826. (SCI 三區)

2019 

[10] S. Li*, H. Lv (推免至華東師範大學讀博), Y. Yu, X. Ye, B. Li, S. Yang, Y. Mo, X. Kong*. Domino N-/C- or N-/N-/C-arylation of imidazoles to yield polyaryl imidazolium salts via atom-economical use of diaryliodonium salts. Chem. Commun. 2019, 55, 11267−11270. (SCI一區)

 

2018以前

[9] S. Li, J. Tang, Y. Zhao, R. Jiang, T. Wang, G. Gao*, J. You*, Cu-Catalyzed Controllable C−H Mono-/Di-/Triarylations of Imidazolium Salts for Ionic Functional Materials, Chem. Commun. 2017, 53, 3489−3492.

[8] S. Li, F. Yang, T. Lv, J. Lan, Ge Gao*, J, You*, Synthesis of unsymmetrical imidazolium salts by direct quaternization of N-substituted imidazoles using arylboronic acids, Chem. Commun. 2014, 50, 3941−3943.

[7] Y. Zhao, S. Li, X. Zheng, J. Tang, Z. She, G. Gao*, J. You*, Rh/Cu-Catalyzed Cascade [4+2] Vinylic C−H O-Annulation and Ring Contraction of a-Aryl Enones with Alkynes in Air, Angew. Chem. Int. Ed. 2017, 56, 4286−4289. （國際頂級期刊）

[6] J. Tang, S. Li, Z. Liu, Y. Zhao, Z. She, V.s D. Kadam, G. Gao*, J. Lan, J. You*，Cascade C−H Annulation of Aldoximes with Alkynes Using O2 as the Sole Oxidant: One-Pot Access to Multisubstituted Protoberberine Skeletons, Org. Lett. 2017, 19, 604-607.

[5] X. Li, S. Li, G. Gao, D. Wu, J. Lan*, R. Wang*, J. You*，High Performance Ruthenium Sensitizers Containing Imidazoliums as Counterions for the Efficient Dye-Sensitization in Water, ChemSusChem. 2017, 10, 2914−29121. 

[4] H. Zhou, Y., Zhao, G. Gao*, S. Li, J. Lan, J. You*, Highly Selective Fluorescent Recognition of Sulfate in Water by Two Rigid Tetrakisimidazolium Macrocycles with Peripheral Chains, J. Am. Chem. Soc. 2013, 135, 14908−14911. （國際頂級期刊）

[3] Z. He, X. Qi, S. Li, Y. Zhao, G. Gao*, Y. Lan*, Y. Wu, J. Lan, J. You*, Transition-Metal-Free Formal Decarboxylative Coupling of α-Oxocarboxylates with α-Bromoketones under Neutral Conditions: A Simple Access to 1,3-Diketones, Angew. Chem. Int. Ed. 2015, 54, 855−859.（國際頂級期刊）

[2] Y. Zhao, Z. He, S. Li, J. Tang, G. Gao*, J. Lan, J. You*, An Air-stable Half-sandwich Ru^II complex as an efficient Catalyst for [3+2] Annulation of 2-Arylcyclo-2-enones with Alkynes, Chem. Commun. 2016, 52, 4613−4616.

[1] Z. He, X. Qi, Z. She, Y. Zhao, S. Li, J. Tang, G. Gao*, Y. Lan*, J. You*, Room-Temperature Coupling/Decarboxylation Reaction of α‑Oxocarboxylates with α‑Bromoketones: Solvent-Controlled Regioselectivity for 1,2- and 1,3-Diketones, J. Org. Chem. 2017, 82, 1403−1411.

六、授權發明專利

[1] 李世清，李永樹，梁霞靜，劉運烽，陳紫園，潘梅玲. 聯苯基橋聯雙苯并咪唑鎓的制備方法及其應用，中國發明專利，ZL 201811538437.5，2022年3月22日授權。

[2] 李世清，呂洪旭，餘雨，葉秀青，黎柏松，楊松明，莫炎儒. 一種由二芳基碘鎓鹽與咪唑合成五芳基咪唑鎓鹽的方法，中國發明專利，ZL 201910658316.2，2022年8月9日授權。

七、招生與聯系方式

招生：招收化學、化學工程與技術、材料與化工等專業一志願以及調劑錄取的碩士研究生，歡迎有機化學愛好者報考本課題組！也歡迎喜歡科研的本科生加入課題組！

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