王凱，漢族，湖南汨羅人。博士，教授。
電子郵箱：kaiwang@glut.edu.cn
一、教育工作經曆
2016.09至今：太阳成tyc9728，太阳成tyc9728任教。
2009.07-2016.07：桂林師範高等專科學校，化學與藥學系任教。
2011.09-2015.06：南京大學，化學化工學院，無機化學專業，獲理學博士學位。
2006.09-2009.06：廣西師範大學，化學與藥學學院，有機化學專業，獲理學碩士學位。
2002.09-2006.06：廣西師範大學，化學與藥學學院，化學專業，獲理學學士學位。
二、教學工作
主要承擔《無機化學》、《普通化學》、《大學化學》等本科生課程，《單晶結構解析》等研究生課程。主持廣西高等教育本科教學改革工程項目1項，參編《普通化學》與《有機化學化學》教材2部。
教學/指導學生獲獎：
1）廣西高校大學生化學實驗技能競賽“優秀教練員”。
2）第八屆廣西高校青年教師教學競賽三等獎。
3）太阳成tyc9728第十八屆“十佳授課教師”。
4）指導本科生獲“挑戰杯”廣西大學生課外學術科技作品競賽特等獎1項、二等獎1項。
5）指導本科生獲廣西高校大學生化學化工類論文及設計競賽一等獎1項、二等獎3項。
6）指導本科生獲廣西高校大學生化學實驗技能競賽一等獎5項，二等獎2項，三等獎3項。
7）指導碩士研究生林超斌、郭柯柯獲廣西青年學術年會論文一等獎1項。
8）指導郭柯柯碩士學位論文獲評2019年太阳成tyc9728優秀研究生學位論文。
9）指導蘇森達碩士學位論文獲評2019年太阳成tyc9728優秀研究生學位論文。
10）指導羅學晶碩士學位論文獲評2022年太阳成tyc9728優秀研究生學位論文。
11）指導朱孟孟碩士學位論文獲評2023年太阳成tyc9728優秀研究生學位論文。
12）指導蔡展婷碩士學位論文獲評2024年太阳成tyc9728優秀研究生學位論文。
三、科研工作
主要從事稀土分子基材料的設計合成及其磁性、光響應性與光催化活性研究。主持國家自然科學基金2項、廣西自然科學基金3項、廣西高校科研項目1項；作為第一作者或通訊作者已在Chinese Chem. Lett.、Chem. Commum.、Inorg. Chem.、J Org. Chem.、Cryst. Growth Des.、Dalton Trans.、Adv. Synth. Catal.等重要學術刊物上發表SCI論文30餘篇，獲授權專利6件，參編學術專著1部；曾獲2012年廣西自然科學獎三等獎1項。
主持科研項目：
1）國家自然科學基金：含主客體型π-π供受體對的光響應性稀土分子磁體研究。
2）國家自然科學基金：稀土單分子磁體中單離子磁各向異性與磁交換作用協同的機制與調控研究。
3）廣西自然科學基金：光刺激響應性Dy基分子磁體的設計合成與響應機制研究。
4）廣西自然科學基金：雙核稀土單分子磁體的合成、弛豫機理與磁構關系研究。
5）廣西自然科學基金：配體調控的Gd基配合物合成及其磁制冷性質研究。
研究論文：
1）Qin, Y.; Wu, C. E.; Li, C. J.; Cai, Z. T.; Hu, B.; Wang, Q. B.; Chen, Z. L.*; Liang, F. P.*; Wang, K.* Supermolecular aggregates of mononuclear and asymmetric dinuclear dysprosium single-molecule magnets assembled by intermolecular hydrogen bonds. Cryst. Growth Des., 2024, 24, 6148−6157.
2）Liu, Y.; Guo, K. K.; Wu, J. L.; Tang, S.*; Teng, Q. H.*; Liang, F. P.; Wang, K.* From Dy-chain to Dy-dimer: significant structural variation induced only by counter cations and slow magnetic relaxation behaviors. J Mol. Struct., 2024, 1316, 139038.
3）Cai, Z. T.; Peng, S.; Gao, J. F.; Zhu, Z. R.*; Liang, F. P.*, Wang, K.* Spontaneous resolution and magnetic properties of lanthanide metal organic frameworks based on oxydiacetate. Polyhedron, 2024, 260, 117104.
4）Huang, F. P.; Qin, W. J.; Pan, X. Y.; Yang, K.; Wang, K.*; Teng, Q. H.* Visible-light induced chemodivergent synthesis of tetracyclic quinazolinones and 3-iminoisoindoliones via substrate control strategy. J Org. Chem., 2024, 89, 4395–4405.
5）Pan, X. Y.; Sun, G. X.; Huang, F. P.; Qin, W. J.; Teng, Q. H.*; Wang, K.* Photogenerated chlorine radical activated C(sp3)–H bonds of alkylbenzenes to access quinazolinones. Org. Biomol. Chem., 2024, 22, 2968–2973.
6）Peng S.; Ouyang, X. M.; Wang, Y. H.; Teng, Q. H.*; Li, Y.; Zhang, X. Q.; Hu, Z. B.; Wang, K.*; Liang, F. P.* In situ synthesized homochiral dysprosium-oxo clusters with threonine Schiff bases, Chinese Chem. Lett., 2023, 34, 108044.
7）Luo, X. J.; Liu, Y.; Pan, H. D.; Peng, S.; Hu, Z. B.*; Teng, Q. H.; Li, Y.; Liang, F. P.*, Wang, K.* Photoresponsive magnetic relaxation behavior of a highly stable π···π interaction-stacked framework based on a DyIII single-ion magnet. Cryst. Growth Des., 2023, 23, 4825–4835.
8）Chen, J. H.; Peng, S.; Pan, H. D.; Wu, C. E.; Teng, Q. H.; Li, Y.; Zhang, X. Q.; Liang, F. P.*; Wang, K.* Dysprosium clusters from 3-ethoxysalicylidene terminal-decorated acylhydrazone ligands: in situ ligand-transformation-assisted assembly and zero field single-molecule magnet behaviors. Cryst. Growth Des., 2023, 23, 4927–4938.
9）Teng, Q. H.*; Sun, G. X.; Huang, F. P.; Wang, K.*; Liang, F. P.* Visible-light induced cerium-catalyzed N-demethylation of N-methyl amides under air conditions. Adv. Synth. Catal., 2023, 365, 307–311.
10）Liu, L.; Yang, P. P.; Qiu, Z. H.*; Wang, K.*; Liu, D. C.; Liang, Y. N.; Hu, H. C.; Zou, H. H.; Liang, F. P.; Chen, Z. L*. Russian doll-like 3d-4f cluster wheels with slow relaxation of magnetization. Molecules, 2023, 28, 5906.
11）Wang, Y. H.; Qin, Y.; Tang, S.; Teng, Q. H.*; Zhu, M. M.; Peng, S.; Wang, K.*; Liang, F. P.* Asymmetric {Dy4} metallogrid and double-layered {Dy8} cage clusters from carboxylic decorated o-vanillin schiff bases: syntheses, topological variation, and single molecule magnet behaviors. New J Chem., 2023, 47, 2052–2059.
12）Zhu, M. M.; Pan, H. D.; Teng, Q. H.*; Liang, F. P.*, Wang, K.* Slow magnetic relaxation behavior of a {Dy2} complex based on large π-conjugated bridging ligand. Polyhedron, 2023, 232, 1116271.
13）Pan, H. Dong.; Wu, C. E., Chen, J. H.; Li, Y.; Zhang, X. Q.; Teng, Q. H.*; Wang, K.*; Liang, F. P.* A pair of 2D MOFs based on [Tm2] secondary building units: syntheses, structural variation and magnetic properties. J Clust. Sci., 2023, 34, 1769–1776.
14）Kong, F. Y.; Han, H. Z.; Huang, S. X.; Teng, Q. H.; Li, Y.; Zhang, X. Q.; Zhu, L.*; Wang, K.*; Liang, F. P.* A pair of chiral dysprosium single-ion magnets with 2,6-bis[(4S/4R)4-phenyl-2-oxazolinyl]pyridine and hexafluoroacetylacetonate ligands. Russ. J. Coordin. Chem., 2022, 48, 667–674.
15）Teng, Q. H.; Sun, G. X.; Luo, S. Y.; Wang, K.*; Liang, F. P.* Design, syntheses and antitumor activities evaluation of 1,5-diaryl substituted pyrazole secnidazole ester derivatives. J Heterocyclic Chem., 2021, 58, 1656–1664.
16）Xu, F.; Luo, X. J.; Wu, C. E.; Liao, B. Y.; Wang, K.*; Liang, F. P.* A quasi-liner {MnIIDyIIIMnII} cluster featuring in situ Schiff base ligand transformation. J Clust. Sci., 2021, 32, 1411–1418.
17）Huang, S. X.; Xu, F.; Qi, S. J.; Wang, K.*; Li, Y.; Zhang, S. H.; Zhang, X. Q.; Luo, S. Y.*; Liang, F. P.* A double-layered {Cu9} nanocage with diacylhydrazine: synthesis, structure and magnetic properties. J Clust. Sci., 2021, 32, 765–772.
18）Lin, C. B.; Guo, K. K.; Guo, W. X.; Wang, Y. H.; Wang, K.*; Li, Y.; Zhang, S. H.; Zhang, X. Q.; Zhang, Y. Q.*; Liang, F. P.* Rationally designing MOFs based on [Ln2] magnetic building blocks utilizing 2-hydroxyisophthalate and fine-tuning the magnetic properties of Dy analogues by terminal coordinated solvents. Inorg. Chem., 2020, 59, 16924−16935.
19）Su, S. D.; Li, J. X.; Xu, F.; Wang, C. X.; Wang, K.*; Li, Y.; Zhang, S. H.; Zhang, X. Q.; Zhang, Y. Q.*; Liang, F. P.* DyIII single-molecule magnets from ligands incorporating both amine and acylhydrazine Schiff base groups: the centrosymmetric {Dy2} displaying dual magnetic relaxation behaviors. Dalton Trans., 2020, 49, 15739–15749.
20）Su, S. D.; Ou-Yang, X. M.; Guo, K. K.; Lin, Q. M.; Li, Y.; Wang, K.*; Luo, S. Y.*; Liang, F. P.* Synthesis, structure and magnetic properties of a Fe(III) [24-azaMC-8] azametallacrown nanocluster with diacylhydrazine ligand. J Clust. Sci., 2019, 30, 863–868.
21）Guo, K. K.; Su, S. D.; Shen, Y. L.; Wang, K.*; Li, Y.; Zhang, X. Q.; Li, B.*; Zou, H. H.; Liang, F. P.* A [Cu3] cluster-based chain featuring linkages of acylhydrazone N–N Single Bonds and Cl- ions: synthesis, structure and magnetic properties. J Clust. Sci., 2019, 30, 219–224.
22）Wang, K.; Chen, Z. L.; Zou, H. H.; Zhang, S. H.; Li, Y.; Zhang, X. Q.; Sun, W. Y.; Liang, F. P.* Diacylhydrazone assembled {Ln11} nanoclusters featuring a “double-boats conformation” topology: synthesis, structures and magnetism. Dalton Trans., 2018, 47, 2337–2343.
23）Wang, K.; Tang S.; Hu, Z. B.; Zou, H. H.; Wang, X. L.; Zhang, S. H.; Li, Y.; Chen, Z. L.; Liang, F. P.* A family of 3d metal clusters based on N–N single bonds bridged quasi-linear trinuclear cores: the Mn analogue displaying single-molecule magnet behavior. RSC Adv., 2018, 8, 6218–6224.
24）Wang, K.; Chen, Z. L.; Zou, H. H.; Li, Y.; Liang, F. P.* A series of 3d complexes from in-situ reactions of a flexible diacylhydrazine ligand: synthesis, structures and magnetic properties. Transit. Metal Chem., 2017, 42, 17–23.
25）Wang, K.; Chen, Z. L.; Zou, H. H.; Hu, K.; Li, H. Y.; Zhang, Z.; Sun, W. Y.; Liang, F. P.* A single-stranded {Gd18} nanowheel with symmetric polydentate diacylhydrazone ligand. Chem. Commun., 2016, 52, 8297−8300.
26）Wang, K.; Huang, X. K.; Zhu. L.; Chen, Z. L.; Liang, F. P.* A chain cadmium(II) coordination polymer with diacylhydrazide: synthesis, crystal structure and luminescent property. Chin. J. Struct. Chem., 2016, 35, 1912-1919.
27）Wang, K.; Chen, Z. L.; Zou, H. H.; Zhang, Z.; Sun, W. Y.; Liang, F. P.* Two types of Cu-Ln heterometallic coordination polymers with 2-hydroxyl isophthalate: syntheses, structures and magnetic properties. Cryst. Growth Des., 2015, 15, 2883−2890.
28）Wang, K.; Zou, H. H.; Chen, Z. L.; Zhang, Z.; Sun, W. Y.; Liang, F. P.* One-dimensional Co(II)/Ni(II) complexes of 2−hydroxyl isophthalate: structures and magnetic properties. J. Solid State Chem., 2015, 226, 36−41.
29）Wang, K.; Zou, H. H.; Chen, Z. L.; Zhang, Z.; Sun, W. Y.; Liang, F. P.* A series of 3D metal organic frameworks based on [24-MC-6] metallacrown clusters: structure, magnetic and luminescent properties. Dalton Trans., 2014, 43, 12989−12995.
30）Wang, K.; Liu, X. X.; Yi, X. H.; Wang, H. S.; Zhang, Y.; Pan, Y. M.* Synthesis and metal ion binding activity of methyl 12-amino-13-nitro-7-oxo dehydrodeisopropylabietate derivatives. Med. Chem. Res., 2012, 21, 2494−2500.
31）Wang, K.; Zhang, Y.; Ekunwe, S. I. N.; Yi, X. H.; Liu, X. X.; Wang, H. S.; Pan, Y. M.* Antioxidant activities and inhibition effect of esculetin from Cortex Fraxini on the growth of human colon carcinoma (HT-29) cells. Med. Chem. Res., 2011, 20, 968–974.
32）Wang, K.; Pan, Y. M.*; Wang, H. S.; Zhang, Y.; Lei, Q.; Zhu, Z. R.; Li, H. Y.; Liang, M. Antioxidant activities of Liquidambar formosana Hance leaf extracts. Med. Chem. Res., 2010, 19, 166−176.
授權專利：
1）王凱，王亦寒，徐凡，滕青湖；一種镝-镧異稀土配位聚合物及其分步合成方法與應用；申請(專利)号：CN202211545653.9；授權公告号：CN115850716B。
2）王凱，羅學晶，滕青湖，梁福沛；一種基于不對稱雙核镝配合物的單分子磁體及其制備方法；申請(專利)号：CN202210213118.7；授權公告号：CN114573609B。
3）王凱，朱孟孟，滕青湖，梁福沛；一種基于雙水楊醛縮氮氧吡啶-2,6-二甲酰腙的稀土單離子磁體及其制備方法；申請(專利)号：CN202111510152.2；授權公告号：CN114133407B。
4）王凱，王亦寒，秦雨，梁福沛；一種有序封裝四硫富瓦烯客體的光刺激響應性铕基金屬有機框架；申請(專利)号：CN202211543450.6；授權公告号：CN115746326B。
5）王凱，羅學晶，滕青湖，梁福沛；一種兼具高穩定性與光刺激響應性的镝基單離子磁體超分子框架及其合成方法；申請(專利)号：CN202210262448.5；授權公告号：CN114835909B。
6）王凱，郭柯柯，黃生學，梁福沛；一種具有磁制冷效應的二維钆基化合物及其制備方法；申請(專利)号：CN201810861783.0；授權公告号：CN109134874B。
